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E-mail: michael@shboqu.com   |   Expert in Water Quality Measurement and Water Treatment Project

Main features and measurement principle of residual chlorine meter

by:BOQU     2023-04-06
The residual chlorine meter is an online residual chlorine analysis instrument. It is composed of a residual chlorine sensor and a residual chlorine meter. It can measure residual chlorine and temperature at the same time. It is widely used in electric power, water supply, medicine, chemical industry, food and other industries. Chlorine is measured continuously. The residual chlorine meter is composed of signal measurement, calculation, display, network communication and panel instructions. The residual chlorine electrode includes a temperature electrode and a pH electrode to amplify the sampled signal through the instrument amplifier into a low-resistance voltage signal and send it to the calculation to display the measured value. The residual chlorine electrode uses gold (Pu) as the cathode, silver (Ag) as the anode, and the filling solution, that is, the electrolyte is 0.1MKCl, and a permeable membrane with selective hypochlorous acid (HOCl) is used. This permeable membrane can only contain hypochlorous acid molecules. Permeable freely, while hypochlorite ion (ClO-) and chlorine are impenetrable. During measurement, a polarization voltage is applied between the anode and the cathode, and HOCl molecules are consumed at the cathode through the permeable membrane, forming a current proportional to the concentration of hypochlorous acid to flow through the electrode. The instrument detects this current and converts it into the concentration of hypochlorous acid through calculation. , At the same time, the pH and temperature electrodes detect the pH value and temperature of the solution, and the meter converts the residual chlorine content in the water according to the detected pH and temperature. Main features Menu design: Object-oriented menu design is adopted to make the operation simple and clear. Multi-screen display: There are 3 display modes in the instrument, which is convenient for users to have different requirements for display modes. Residual chlorine calibration: Provide residual chlorine zero point calibration and slope calibration, and the menu design is clear and clear. Digital clock: provide timing function. Wide screen display: 12864 LCD with soft backlight and clear display. Meter stability: The watchdog function ensures the normal and continuous operation of the meter. Measuring principle When the working electrode is a gold electrode (Pt) and the counter electrode is a silver/silver chloride electrode (Ag/AgCl), the reaction formula is as follows: Working electrode WE: H+ + 2e + OCL → OH + Cl pair Electrode CE: 2Ag - 2e → 2Ag + According to the Ilkovie equation: Diffusion current I = nAFDc/&In the formula: n—the number of electrons exchanged per unit area A—the surface area of ​​the working electrode F—the normal position constant D—the diffusion coefficient of the depolarizer c—the concentration of the depolarizer&The thickness of the diffusion layer between the working electrode and the solution
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